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Prepared at the 44th JECFA (1995), published in FNP 52 Add 3 (1995) superseding specifications prepared at the 39th JECFA (1992), published in FNP 52 Add 1 (1992) |
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SYNONYMS |
INS No. 493 |
DEFINITION |
A mixture of the partial esters of sorbitol and its mono- and dianhydrides with edible lauric acid |
C.A.S. number |
1338-39-2 |
Structural formula |
Contains lauric acid esterified with polyols derived from sorbitol including the following types:
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Assay |
Saponification of 100 g of the sample yields not less than 36 g and not more than 49 g of polyols, and not less than 56 g and not more than 68 g of fatty acids. The polyol content shall be not less than 95% of a mixture of sorbitol, 1,4-sorbitan and isosorbide. |
DESCRIPTION |
Amber-coloured oily viscous liquid, light cream to tan beads or flakes or a hard, waxy solid with a slight odour |
FUNCTIONAL USES |
Emulsifier, stabilizer |
CHARACTERISTICS | |
IDENTIFICATION | |
Solubility |
Dispersible in hot and cold water |
PURITY | |
Water |
Not more than 2% (Karl Fischer Method) |
Sulfated ash |
Not more than 0.5% |
Acid value |
Not more than 7 |
Saponification value |
Not less than 155 and not more than 170 |
Hydroxyl value |
Not less than 330 and not more than 358 |
Arsenic |
Not more than 3 mg/kg (Method II) |
Heavy metals |
Not more than 10 mg/kg Test 2 g of the sample as directed in the Limit Test (Method II) |
METHOD OF ASSAY |
Transfer about 25 g of the sample, accurately weighed, into a 500-ml round-bottom flask, add 250 ml of alcohol and 7.5 g of potassium hydroxide, and mix. Connect a suitable condenser to the flask, reflux the mixture for 1 to 2 h, and then transfer to an 800-ml beaker, rinsing the flask with about 100 ml of water and adding it to the beaker. Heat on a steam bath to evaporate the alcohol, adding water occasionally to replace the alcohol, and evaporate until the odor of alcohol can no longer be detected. Adjust the final volume to about 250 ml with hot water. Neutralize the soap solution with dilute sulfuric acid (1 in 2), add 10% in excess, and heat, while stirring, until the fatty acid layer separates. Transfer the fatty acids to a 500-ml separator, wash with three or four 20-ml portions of hot water to remove polyols, and combine the washings with the original aqueous polyol layer from the saponification. Extract the combined aqueous layer with three 20-ml portions of petroleum ether, add the extracts to the fatty acid layer, evaporate to dryness in a tared dish, cool and weigh.
Neutralize the polyol solution with a 1 in 10 solution of potassium hydroxide to pH 7 using a suitable pH meter. Evaporate this solution to a moist residue, and separate the polyols from the salts by several extractions with hot alcohol. Evaporate the alcohol extracts on a steam bath to dryness in a tared dish, cool, and weigh. Avoid excessive drying and heating. |