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SORBITAN MONOPALMITATE

Prepared at the 17th JECFA (1973), published in FNP 4 (1978) and in FNP 52 (1992)


SYNONYMS

INS No. 495

DEFINITION

A mixture of the partial esters of sorbitol and its mono- and dianhydrides with edible commercial palmitic acid

C.A.S. number

26266-57-9

Structural formula

Contains palmitic acid esterified with polyols derived from sorbitol including the following types:

Assay

Saponification of 100 g of the sample yields approximately 37 g of polyols and 65 g of fatty acid. The polyol content shall be approximately 95% of a mixture of sorbitol, 1,4-sorbitan and isosorbide

DESCRIPTION

Light cream to tan beads or flakes or hard, waxy solid with a characteristic odour

FUNCTIONAL USES

Emulsifier

CHARACTERISTICS

IDENTIFICATION

Solubility

Soluble at temperatures above its melting point in ethanol, methanol, ether, ethylacetate, aniline, toluene, dioxane, petroleum ether and carbon tetrachloride; insoluble in cold water but dispersible in warm water.

Congealing range

45 - 47o

Infrared absorption

The infrared spectrum of the sample is characteristic of a partial fatty acid ester of a polyol

PURITY

Water

Not more than 1.5% (Karl Fischer Method)

Acid value

Not less than 4.0 and not more than 7.5

Saponification value

Not less than 140 and not more than 150

Hydroxyl value

Not less than 270 and not more than 305

Arsenic

Not more than 3 mg/kg (Method II)

Heavy metals

Not more than 10 mg/kg

Test 2 g of the sample as directed in the Limit Test (Method II)

METHOD OF ASSAY

Proceed as directed under the Sorbitan Ester Content.


Source: Joint FAO/WHO Expert Committee on Food Additives (JECFA)


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